Is HBr Ionic or Covalent? (And Why?)

Is HBr Ionic or Covalent

HBr is a covalent (polar covalent) compound because when one nonmetal combines with another nonmetal, it usually forms a covalent compound. Here, H is a nonmetal and Br is also a nonmetal. So when they combine, it forms a covalent compound.

Well, now you have got to know that Hydrogen bromide (HBr) is a covalent compound, but let me explain the in-depth reason why HBr is a covalent compound.

If you are a visual learner like me, then here is a short one minute video for you.

Why is HBr a Covalent compound?

As mentioned above, you can simply remember that when the nonmetal combines with another nonmetal, the bond between them is a covalent bond.

Here in HBr, the H atom is a nonmetal and the Br atom is also a nonmetal.

Hence the bond between them is a covalent bond.

How does the covalent bond form between H and Br?

In HBr, there are two atoms;
H and Br.

About Hydrogen (H):

Hydrogen atom have 1 electron.

It has only 1 orbit and there is only 1 electron in this orbit.

Now in order to achieve a stable duplet, the Hydrogen atom needs 1 more electron.

hydrogen

Hence during the chemical reaction, the Hydrogen atom will gain 1 electron from the combining atom to form a stable duplet.

About Bromine (Br):

Bromine atom have 35 electrons.

The electrons arrangement in Bromine (Br) is 2, 8, 18, 7.

So the outermost orbit of Bromine atom has 7 electrons.

Now in order to achieve a stable octet, the Bromine atom needs 1 more electron.

bromine

Hence during the chemical reaction, the Bromine atom will gain 1 electron from the combining atom to form a stable octet.

What happens when H and Br combine?

When H and Br combine with each other, the Hydrogen atom and Bromine atom mutually share their 1-1 electrons with each other.

Because of this the hydrogen atom will have 2 electrons in its outermost orbit and similarly the bromine atom will also have 8 electrons in its outermost orbit.

hbr

As a result, the hydrogen atom will have a stable duplet and the bromine atom will have a stable octet.

And finally, as the bond formed between the hydrogen and bromine is due to the mutual sharing of electrons, it is considered a covalent bond.

Thus, HBr is a covalent compound.

Is HBr polar covalent or nonpolar covalent?

In order to know whether Hydrogen bromide (HBr) is a polar covalent molecule or nonpolar covalent molecule, we have to check the electronegativity difference of the combining atoms.

If the electronegativity difference (ΔEN) is less than 0.4, then the bond is nonpolar covalent bond. 

If the electronegativity difference (ΔEN) is between 0.4 to 1.7, then the bond is polar covalent bond.[1][2][3][4]

Now the electronegativity of Hydrogen and Bromine are mentioned below. (You can see the electronegativity of all the elements from this electronegativity chart).

  • Electronegativity of Hydrogen (H) = 2.2 
  • Electronegativity of Bromine (Br) = 2.96

So for HBr, the electronegativity difference (ΔEN) = 2.96 – 2.2 = 0.76

This value lies between 0.4 to 1.7, which indicates that the bond between Hydrogen (H) and Bromine (Br) is polar covalent bond.

hbr

Hence, HBr is a polar covalent molecule.

I hope you have understood the reason why HBr is a polar covalent compound.

Check out other compounds to see whether they are ionic or covalent;
Is LiF Ionic or Covalent?
Is MgSO4 Ionic or Covalent?
Is LiCl Ionic or Covalent?
Is H2 Ionic or Covalent?
Is CF4 Ionic or Covalent? 

Author

Jay is an educator and has helped more than 100,000 students in their studies by providing simple and easy explanations on different science-related topics. With a desire to make learning accessible for everyone, he founded Knords Learning, an online learning platform that provides students with easily understandable explanations.

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