Lewis Structure of AlF3 (With 5 Simple Steps to Draw!)

Lewis Structure of AlF3

Ready to learn how to draw the lewis structure of AlF3?


Here, I have explained 5 simple steps to draw the lewis dot structure of AlF3 (along with images).

So, if you are ready to go with these 5 simple steps, then let’s dive right into it!

Lewis structure of AlF3 contains three single bonds between the Aluminum (Al) atom and each Fluorine (F) atom. The Aluminum atom (Al) is at the center and it is surrounded by 3 Fluorine atoms (F). The Aluminum atom does not have a lone pair while all three fluorine atoms have three lone pairs each.

Let’s draw and understand this lewis dot structure step by step.

(Note: Take a pen and paper with you and try to draw this lewis structure along with me. I am sure you will definitely learn how to draw lewis structure of AlF3).

5 Steps to Draw the Lewis Structure of AlF3

Step #1: Calculate the total number of valence electrons

Here, the given molecule is AlF3. In order to draw the lewis structure of AlF3, first of all you have to find the total number of valence electrons present in the AlF3 molecule.
(Valence electrons are the number of electrons present in the outermost shell of an atom).

So, let’s calculate this first.

Calculation of valence electrons in AlF3

  • For Aluminum: 

Aluminum is a group 13 element on the periodic table. [1]

Hence, the valence electrons present in aluminum is 3 (see below image).

  • For Fluorine: 

Fluorine is a group 17 element on the periodic table. [2]

Hence, the valence electrons present in fluorine is 7 (see below image).

Hence in a AlF3 molecule, 

Valence electrons given by Aluminum (Al) atom = 3
Valence electrons given by each Fluorine (F) atom = 7
So, total number of Valence electrons in AlF3 molecule = 3 + 7(3) = 24

Step #2: Select the center atom

While selecting the center atom, always put the least electronegative atom at the center.

(Remember: Fluorine is the most electronegative element on the periodic table and the electronegativity decreases as we move right to left in the periodic table as well as top to bottom in the periodic table). [3]

Here in the AlF3 molecule, if we compare the aluminum atom (Al) and fluorine atom (F), then aluminum is less electronegative than fluorine.

So, aluminum should be placed in the center and the remaining 3 fluorine atoms will surround it.

step 1

Step #3: Put two electrons between the atoms to represent a chemical bond

Now in the above sketch of AlF3 molecule, put the two electrons (i.e electron pair) between each aluminum atom and fluorine atom to represent a chemical bond between them.

step 2

These pairs of electrons present between the Aluminum (Al) and Fluorine (F) atoms form a chemical bond, which bonds the aluminum and fluorine atoms with each other in a AlF3 molecule.

Step #4: Complete the octet (or duplet) on outside atoms. If the valence electrons are left, then put the valence electrons pair on the central atom

Don’t worry, I’ll explain!

In the Lewis structure of AlF3, the outer atoms are fluorine atoms.

So now, you have to complete the octet on these fluorine atoms (because fluorine requires 8 electrons to have a complete outer shell).

step 3

Now, you can see in the above image that all the fluorine atoms form an octet.

Also, all the 24 valence electrons of AlF3 molecule (as calculated in step #1) are used in the above structure. So there are no remaining electron pairs.

Hence there is no change in the above sketch of AlF3.

Let’s move to the next step.

Step #5: Check the stability of lewis structure by calculating the formal charge on each atom

Now, you have come to the final step and here you have to check the formal charge on aluminum atom (Al) as well as each fluorine atom (F).

For that, you need to remember the formula of formal charge;

Formal charge = Valence electrons – Nonbonding electrons – (Bonding electrons)/2

step 4
  • For Aluminum:
    Valence electrons = 3 (as it is in group 13)
    Nonbonding electrons = 0
    Bonding electrons = 6
  • For Fluorine:
    Valence electron = 7 (as it is in group 17)
    Nonbonding electrons = 6
    Bonding electrons = 2
Formal charge=Valence electronsNonbonding electrons(Bonding electrons)/2

So you can see above that the formal charges on aluminum as well as fluorine are “zero”.

Hence, there will not be any change in the above structure and the above lewis structure of AlF3 is the final stable structure only.

Each electron pair (:) in the lewis dot structure of AlF3 represents the single bond ( | ). So the above lewis dot structure of AlF3 can also be represented as shown below.

alf3 lewis structure

Related lewis structures for your practice:
Lewis Structure of IBr
Lewis Structure of SeCl4
Lewis Structure of HOF
Lewis Structure of XeO2F2
Lewis Structure of XeH4 

Article by;


Jay is an educator and has helped more than 100,000 students in their studies by providing simple and easy explanations on different science-related topics. With a desire to make learning accessible for everyone, he founded Knords Learning, an online learning platform that provides students with easily understandable explanations.

Read more about our Editorial process.

Leave a Comment