Lewis Structure of GeCl4 (With 6 Simple Steps to Draw!)

Lewis Structure of GeCl4

Ready to learn how to draw the lewis structure of GeCl4?


Here, I have explained 6 simple steps to draw the lewis dot structure of GeCl4 (along with images).

So, if you are ready to go with these 6 simple steps, then let’s dive right into it!

Lewis structure of GeCl4 contains four single bonds between the Germanium (Ge) atom and each Chlorine (Cl) atom. The Germanium atom (Ge) is at the center and it is surrounded by 4 Chlorine atoms (Cl). The Germanium atom does not have a lone pair while all four chlorine atoms have three lone pairs each.

Let’s draw and understand this lewis dot structure step by step.

(Note: Take a pen and paper with you and try to draw this lewis structure along with me. I am sure you will definitely learn how to draw lewis structure of GeCl4).

6 Steps to Draw the Lewis Structure of GeCl4

Step #1: Calculate the total number of valence electrons

Here, the given molecule is GeCl4. In order to draw the lewis structure of GeCl4, first of all you have to find the total number of valence electrons present in the GeCl4 molecule.
(Valence electrons are the number of electrons present in the outermost shell of an atom).

So, let’s calculate this first.

Calculation of valence electrons in GeCl4

  • For Germanium:

Germanium is a group 14 element on the periodic table. [1]

Hence, the valence electrons present in germanium is 4 (see below image).

  • For Chlorine:

Chlorine is a group 17 element on the periodic table. [2]

Hence, the valence electron present in chlorine is 7 (see below image).

Hence in a GeCl4 molecule, 

Valence electrons given by Germanium (Ge) atom = 4
Valence electrons given by each Chlorine (Cl) atom = 7
So, total number of Valence electrons in GeCl4 molecule = 4 + 7(4) = 32

Step #2: Select the center atom

While selecting the center atom, always put the least electronegative atom at the center.

(Remember: Fluorine is the most electronegative element on the periodic table and the electronegativity decreases as we move right to left in the periodic table as well as top to bottom in the periodic table). [3]

Here in the GeCl4 molecule, if we compare the germanium atom (Ge) and chlorine atom (Cl), then germanium is less electronegative than chlorine.

So, germanium should be placed in the center and the remaining 4 chlorine atoms will surround it.

step 1

Step #3: Put two electrons between the atoms to represent a chemical bond

Now in the above sketch of GeCl4 molecule, put the two electrons (i.e electron pair) between each germanium atom and chlorine atom to represent a chemical bond between them.

step 2

These pairs of electrons present between the Germanium (Ge) and Chlorine (Cl) atoms form a chemical bond, which bonds the germanium and chlorine atoms with each other in a GeCl4 molecule.

Step #4: Complete the octet (or duplet) on outside atoms. If the valence electrons are left, then put the valence electrons pair on the central atom

Don’t worry, I’ll explain!

In the Lewis structure of GeCl4, the outer atoms are chlorine atoms.

So now, you have to complete the octet on these chlorine atoms (because chlorine requires 8 electrons to have a complete outer shell).

step 3

Now, you can see in the above image that all the chlorine atoms form an octet.

Also, all the 32 valence electrons of GeCl4 molecule (as calculated in step #1) are used in the above structure. So there are no remaining electron pairs.

Hence there is no change in the above sketch of GeCl4.

Let’s move to the next step.

Step #5: Check whether the central atom has octet or not. If it does not have an octet, then move the electron pair from the outer atom to form a double bond or triple bond

In this step, we have to check whether the central atom (i.e germanium) has an octet or not. 

In simple words, we have to check whether the central Germanium (Ge) atom is having 8 electrons or not.

step 4

As you can see from the above image, the central atom (i.e germanium), has 8 electrons. So it fulfills the octet rule and the germanium atom is stable.

Step #6: Check the stability of lewis structure by calculating the formal charge on each atom

Now, you have come to the final step and here you have to check the formal charge on germanium atom (Ge) as well as each chlorine atom (Cl).

For that, you need to remember the formula of formal charge;

Formal charge = Valence electrons – Nonbonding electrons – (Bonding electrons)/2

step 5
  • For Germanium:
    Valence electrons = 4 (as it is in group 14)
    Nonbonding electrons = 0
    Bonding electrons = 8
  • For Chlorine:
    Valence electron = 7 (as it is in group 17)
    Nonbonding electrons = 6
    Bonding electrons = 2
Formal charge=Valence electronsNonbonding electrons(Bonding electrons)/2

So you can see above that the formal charges on germanium as well as chlorine are “zero”.

Hence, there will not be any change in the above structure and the above lewis structure of GeCl4 is the final stable structure only.

Each electron pair (:) in the lewis dot structure of GeCl4 represents the single bond ( | ). So the above lewis dot structure of GeCl4 can also be represented as shown below.

gecl4 lewis structure

Related lewis structures for your practice:
Lewis Structure of P2O5
Lewis Structure of C2Br4
Lewis Structure of TeBr2
Lewis Structure of AsF5
Lewis Structure of HI 

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Jay is an educator and has helped more than 100,000 students in their studies by providing simple and easy explanations on different science-related topics. With a desire to make learning accessible for everyone, he founded Knords Learning, an online learning platform that provides students with easily understandable explanations.

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